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Publication Detail
Stereoselective Synthesis of Densely Substituted Tetrahydroquinolines by a Conjugate Addition nitro-Mannich Reaction with Carbon Nucleophiles
  • Publication Type:
    Journal article
  • Publication Sub Type:
    Article
  • Authors:
    Anderson JC, Rundell CD
  • Publication date:
    29/10/2015
  • Journal:
    Synlett: accounts and rapid communications in synthetic organic chemistry
  • Print ISSN:
    1437-2096
  • Keywords:
    amines, stereoselective synthesis, cyclisation, imines, quinolines
  • Addresses:
    University College London
    London
Abstract
Conjugate addition of an alkyl group to a series of 2-imino-nitrostyrenes and then addition of trifluoroacetic acid initiates a nitro-Mannich cyclisation to give cis, cis-2,3,4-substituted tetrahydroquinolines in good yield and high diastereoselectivity.
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