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Publication Detail
Statistical mechanical lattice models of endohedral and exohedral xenon adsorption in carbon nanotubes and comparison with Monte-Carlo simulations
  • Publication Type:
    Journal article
  • Publication Sub Type:
    Article
  • Authors:
    Dunne LJ, Manos G, Rekabi M
  • Publisher:
    ELSEVIER SCIENCE BV
  • Publication date:
    27/01/2009
  • Pagination:
    99, 102
  • Journal:
    CHEM PHYS
  • Volume:
    355
  • Issue:
    2-3
  • Print ISSN:
    0301-0104
  • Language:
    EN
  • Keywords:
    Adsorption, Nanotube, Statistical mechanics, Xenon, BENZENE ADSORPTION, PHYSICAL ADSORPTION, ZEOLITES, PHASE, TRANSITIONS, ISOTHERMS, ALKANES, SYSTEMS, PORES
  • Addresses:
    Manos, G
    UCL
    Dept Chem Engn
    London
    WC1E 7JE
    England
Abstract
Adsorption of xenon in carbon nanotubes has been investigated by Kuznetsova et al. [A. Kuznetsova, J.T. Yates Jr., J. Liu, R.E. Smalley, J. Chem. Phys. 112 (2000) 9590] and Simonyan et al. [V. Simonyan, J.K. Johnson, A Kuznetsova, J.T. Yates Jr., J. Chem. Phys. 114 (2001) 4180] where endohedral adsorption isotherms show a step-like structure. A matrix method is used for calculation of the statistical mechanics of a lattice model of xenon endohedral adsorption which reproduces the isotherm structure while exohedral adsorption is treated by mean-field theory. (C) 2008 Elsevier B.V. All rights reserved.
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