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Publication Detail
Effect of peptide orientation on electron transfer
  • Publication Type:
    Journal article
  • Publication Sub Type:
    Article
  • Authors:
    Chaudhry BR, Wilton-Ely JDET, Tabor AB, Caruana DJ
  • Publisher:
    ROYAL SOC CHEMISTRY
  • Publication date:
    2010
  • Pagination:
    9996, 9998
  • Journal:
    PHYS CHEM CHEM PHYS
  • Volume:
    12
  • Issue:
    34
  • Print ISSN:
    1463-9076
  • Language:
    EN
  • Keywords:
    ALKANETHIOL MONOLAYERS, DISTANCE DEPENDENCE, TRANSFER KINETICS, HELICAL PEPTIDES, FERROCENE, GOLD
  • Addresses:
    Tabor, AB
    UCL
    Dept Chem
    London
    WC1H 0AJ
    England
Abstract
We have developed a methodology for the in situ derivatisation of histidine residues in self-assembled monolayers of peptides with redox-active groups, and have shown by electrochemical methods that the average dipole of peptide films on gold affects the heterogeneous electron transfer properties.
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