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Publication Detail
Enhancement of H-2 uptake via fluorination but not lithiation for Zn4N8 and Zn4N6O type clusters
  • Publication Type:
    Journal article
  • Publication Sub Type:
    Article
  • Authors:
    Redshaw C, Jana S, Shang CX, Elsegood MRJ, Lu XS, Guo ZX
  • Publisher:
    ROYAL SOC CHEMISTRY
  • Publication date:
    2010
  • Pagination:
    9055, 9057
  • Journal:
    CHEM COMMUN
  • Volume:
    46
  • Issue:
    47
  • Print ISSN:
    1359-7345
  • Language:
    EN
  • Keywords:
    METAL-ORGANIC FRAMEWORKS, HYDROGEN ADSORPTION, GAS-ADSORPTION, ZINC ALKYLS, OXYGENATION, COMPLEX, STORAGE
  • Addresses:
    Redshaw, C
    Univ E Anglia
    Energy Mat Lab
    Sch Chem
    Norwich
    NR4 7TJ
    Norfolk
    England

    Univ E Anglia
    Sch Environm Sci
    Norwich
    NR4 7TJ
    Norfolk
    England
Abstract
The introduction of fluorinated aryls at zinc in Zn4N8-type (and to a lesser extent Zn4N6O) cages led to enhanced H-2 uptake. Lithium alkoxides have been shown to link such cages (non-fluorinated), but showed no substantial improvement in uptake.
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