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Publication Detail
Multinuclear Zinc Pentafluorobenzene Carboxylates: Synthesis, Characterization, and Hydrogen Storage Capability
  • Publication Type:
    Journal article
  • Publication Sub Type:
    Article
  • Authors:
    Redshaw C, Jana S, Shang CX, Elsegood MRJ, Lu XS, Guo ZX
  • Publisher:
    AMER CHEMICAL SOC
  • Publication date:
    22/11/2010
  • Pagination:
    6129, 6132
  • Journal:
    ORGANOMETALLICS
  • Volume:
    29
  • Issue:
    22
  • Print ISSN:
    0276-7333
  • Language:
    EN
  • Keywords:
    METAL-ORGANIC FRAMEWORKS, INSERTION REACTIONS, ADSORPTION SITES, GAS-ADSORPTION, CARBON-DIOXIDE, NUMBERS, MOF-5
  • Addresses:
    Redshaw, C
    Univ E Anglia
    Sch Chem
    Energy Mat Lab
    Norwich
    NR4 7TJ
    Norfolk
    England

    Univ E Anglia
    Sch Environm Sci
    Norwich
    NR4 7TJ
    Norfolk
    England
Abstract
Three zinc carboxylate complexes, [(C6F5Zn)(4)-Zn(Ar-1)6]center dot 1.5 toluene, [(C6F5Zn)(4)Zn(Ar-2)(6)]center dot 2toluene, and [(Ar-3)(6)Zn-4(mu(4)-O)]center dot MeCN (where Ar-1 = 2-chlorobenzoic acid (1), Ar-2 = 2,4,6-trimethylbenzoic acid (2), and Ar-3 = 3-dimethylaminobenzoic acid (3)), have been prepared from the reaction of (C6F5)(2)Zn center dot toluene and the corresponding functionalized benzoic acid. Complexes 1-3 were structurally characterized and screened for hydrogen absorption (uptake <0.3 wt %).
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