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Publication Detail
Quadruple hydrogen bonded cytosine modules: N-1 functionalised arrays
  • Publication Type:
    Journal article
  • Publication Sub Type:
    Article
  • Authors:
    Lafitte VGH, Aliev AE, Greco E, Bala K, Golding P, Hailes HC
  • Publisher:
    ROYAL SOC CHEMISTRY
  • Publication date:
    2011
  • Pagination:
    1522, 1527
  • Journal:
    NEW J CHEM
  • Volume:
    35
  • Issue:
    7
  • Print ISSN:
    1144-0546
  • Language:
    EN
  • Keywords:
    SUPRAMOLECULAR POLYMERS, CYCLIC DIMERS, SYSTEMS, MOTIFS, NMR
  • Addresses:
    Hailes, HC
    UCL
    Dept Chem
    London
    WC1H 0AJ
    England
Abstract
A ureidocytosine (UCyt) module with a pendant amine linker at N-1 has been prepared for applications in supramolecular quadruple hydrogen bonded array synthesis. Subsequent conjugation to four amine terminated telechelic polymers led to the formation of oligomeric DDAA arrays, as determined by NMR diffusion measurements, establishing that N-1 as well as N-9 ureidocytosine polymeric arrays can readily be accessed.
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