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Publication Detail
Di-mu-chlorido-bis[dichloridobis(methylamido-kappa N)bis(methylamine-kappa N)-titanium(IV)]
  • Publication Type:
    Journal article
  • Publication Sub Type:
    Article
  • Authors:
    Thomas T, Pugh D, Parkin IP, Carmalt CJ
  • Publisher:
    WILEY-BLACKWELL
  • Publication date:
    07/2011
  • Pagination:
    M234, M236
  • Journal:
    ACTA CRYSTALLOGR C
  • Volume:
    67
  • Print ISSN:
    0108-2701
  • Language:
    EN
  • Keywords:
    CRYSTAL-STRUCTURE, COMPLEXES, TITANIUM(IV), CVD
  • Addresses:
    Carmalt, CJ
    UCL
    Dept Chem
    London
    WC1H 0AJ
    England
Abstract
The title compound, [Ti2Cl6(C2H6N)(2)(C2H7N)(2)], is a binuclear octahedral complex lying about an inversion centre. There are four different chloride environments, two terminal [Ti-Cl = 2.2847 (5) and 2.3371 (5) angstrom] and two bridging [Ti-Cl = 2.4414 (5) and 2.6759 (5) angstrom], with the Ti-Cl distances being strongly influenced by both the ligand trans to the chloride and whether or not the chloride anion is bridging between the two Ti-IV centres. The compound forms a two-dimensional network in the solid state, with weak intermolecular C-H center dot center dot center dot Cl interactions giving rise to a planar network in the (10 (2) over bar) plane.
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