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Publication Detail
High-Pressure and -Temperature Ion Exchange of Aluminosilicate and Gallosilicate Natrolite
  • Publication Type:
    Journal article
  • Publication Sub Type:
    Article
  • Authors:
    Hill GL, Bailey E, Stennett MC, Hyatt NC, Maddrell EM, McMillan PF, Hriljac JA
  • Publisher:
    AMER CHEMICAL SOC
  • Publication date:
    07/09/2011
  • Pagination:
    13883, 13885
  • Journal:
    J AM CHEM SOC
  • Volume:
    133
  • Issue:
    35
  • Print ISSN:
    0002-7863
  • Language:
    EN
  • Keywords:
    INDUCED HYDRATION, NAT TOPOLOGY, ZEOLITE, FLEXIBILITY, DISTORTION, DIFFUSION, FRAMEWORK
  • Addresses:
    Hriljac, JA
    Univ Birmingham
    Sch Chem
    Birmingham
    B15 2TT
    W Midlands
    England
Abstract
The simultaneous application of high pressure and high temperature has been used to achieve direct ion exchange of large cesium cations for the small sodium cations found in the zeolite natrolite by putting it into a super-hydrated state with increased pore size. The larger cations remain trapped upon pressure release, and thus, this method is a means of producing new cationic forms of zeolites.
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