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Publication Detail
Spin-based diagnostic of nanostructure in copper phthalocyanine-C60 solar cell blends.
  • Publication Type:
    Journal article
  • Publication Sub Type:
    Journal Article
  • Authors:
    Warner M, Mauthoor S, Felton S, Wu W, Gardener JA, Din S, Klose D, Morley GW, Stoneham AM, Fisher AJ, Aeppli G, Kay CWM, Heutz S
  • Publication date:
  • Pagination:
    10808, 10815
  • Journal:
    ACS Nano
  • Volume:
  • Issue:
  • Status:
  • Country:
    United States
  • Language:
  • Keywords:
    Electric Power Supplies, Electron Spin Resonance Spectroscopy, Fullerenes, Indoles, Models, Molecular, Molecular Conformation, Nanostructures, Organometallic Compounds, Solar Energy
Nanostructure and molecular orientation play a crucial role in determining the functionality of organic thin films. In practical devices, such as organic solar cells consisting of donor-acceptor mixtures, crystallinity is poor and these qualities cannot be readily determined by conventional diffraction techniques, while common microscopy only reveals surface morphology. Using a simple nondestructive technique, namely, continuous-wave electron paramagnetic resonance spectroscopy, which exploits the well-understood angular dependence of the g-factor and hyperfine tensors, we show that in the solar cell blend of C(60) and copper phthalocyanine (CuPc)-for which X-ray diffraction gives no information-the CuPc, and by implication the C(60), molecules form nanoclusters, with the planes of the CuPc molecules oriented perpendicular to the film surface. This information demonstrates that the current nanostructure in CuPc:C(60) solar cells is far from optimal and suggests that their efficiency could be considerably increased by alternative film growth algorithms.
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